Peroxide Chemistry Mechanistic and Preparative Aspects of Oxygen Transfer

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Peroxide Chemistry Mechanistic and Preparative Aspects of Oxygen Transfer

Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer By
2000 | 685 Pages | ISBN: 3527271503 | PDF | 9 MB


This collection of thirty articles on research projects in all areas of peroxide chemistry, i. e. analytical, biochemical, inorganic, organic, organometallic, physical, spectroscopic, and theoretical facets, are the result of a multidisciplinary research program funded by the Deutsche Forschungsgemeinschaft (DFG). The emphasis was to lie on the development of environmentally acceptable, selective (chemo-, regio-, diastereo- and enantioselectivity) oxidations. One chapter focuses on industrial applications which have to meet both economical and ecological demands to remain competitive in the future. Latest results on the consequences of lipid peroxidation in age-dependent diseases, which range from Alzheimer and Parkinson disorders to diabetes, rheumatic arthritis, atherosclerosis and cardiovascular diseases are also presented. Content: Chapter 1 Landmarks in the Development of Organic Peroxide Chemistry (pages 1-38): Manfred SchulzChapter 1 Recent Advances in Homogeneous Catalyzed Epoxidations Using Hydrogen Peroxide or tert.?Butyl Hydroperoxide (pages 39-59): Thomas Kratz and Werner Zei?Chapter 2 Photoinduced Electron?Transfer Reactions of Alkenes and Azide Anions in the Presence of Molecular Oxygen: Formation of 1,2?Azidohydroperoxides and Use As Oxygen?Transfer Reagents (pages 60-77): Axel G. Griesbeck, Jorg Steinwascher and Thomas HundertmarkChapter 3 Preparative Use of Peroxidic Oxidants for Oxygen?Transfer Reactions (pages 78-112): Waldemar Adam, Hans?Georg Degen, Aurelia Pastor, Chantu R. Saha?Moller, Simon B. Schambony and Cong?Gui ZhaoChapter 4 Organosulfonic and Sulfonimidic Peracids - New Oxidants for Diastereoselective and Enantioselective Oxidations of Organic Substrates (pages 113-127): Manfred Schulz and Ralph KlugeChapter 5 Reactive Peroxo Compounds Generated in Situ from Hydrogen Peroxide: Kinetics and Catalytic Application in Oxidation Processes (pages 128-138): Horst Elias and Stephane VayssieChapter 6 Carbonyl O?Oxides and Dioxiranes - From Laboratory Curiosities to Useful Reagents (pages 139-156): K. Block, W. Kappert, A. Kirschfeld, S. Muthusamy, K. Schroeder, W. Sander, E. Kraka, C. Sosa and D. CremerChapter 7 Formation of Dioxiranes and Singlet Molecular Oxygen by the Ketone?Catalyzed Decomposition of Peroxycarboxylic Acids (pages 157-176): Andreas Lange and Hans?Dieter BrauerChapter 1 Age and Age?Dependent Diseases, a Consequence of Lipid Peroxidation (pages 177-208): Gerhard Spiteller, Dieter Spiteller, Wolfgang Jira, Uwe Kie?ling, Angela Dudda, Michael Weisser, Stefan Hecht and Caroline SchwarzChapter 2 New Peroxycarboxylic Acids by Lipase Catalysis: Preparation and Oxidation Properties (pages 209-231): Siegfried Warwel and Mark Rusch gen. KlaasChapter 3 Transition?Metal?Catalyzed Oxyfunctionalization of Catechol and Flavonol Derivatives (pages 232-248): Florian Schweppe, Holger Sirges, Matthias Pascaly, Mark Duda, Cetin Nazikkol, Werner Steinforth and Bernt KrebsChapter 4 Binding and Activation of Dioxygen by Biomimetic Metal Complexes (pages 249-280): Ernst?G. Jager, Jutta Knaudt, Kerstin Schuhmann and Anka GubaChapter 5 Transition Metal?Catalyzed Stereoselective Synthesis of Functionalized Tetrahydrofurans (pages 281-300): Simone Drees, Marco Greb, Jens Hartung and Philipp SchmidtChapter 1 Metallosalen?Catalyzed Asymmetric Oxygen?Transfer Reaction: Dynamics of Salen Ligand Conformation (pages 301-319): Tsutomu KatsukiChapter 2 Transition?Metal Catalyzed Epoxidation of Unfunctionalized Alkenes (pages 320-340): Andreas Scheurer, Paul Mosset, Martina Spiegel and Rolf W. SaalfrankChapter 3 Peroxo Complexes of Molybdenum, Tungsten and Rhenium with Phase Transfer Active Ligands: Catalysts for the Oxidation of Olefins and Aromatics by Hydrogen Peroxide and Bistrimethylsilyl Peroxide (pages 341-364): Carsten Jost, Gunter Wahl, Dirk Kleinhenz and Jorg SundermeyerChapter 4 Kinetic Resolution by Jacobsen Epoxidation as an Easy Route to Podophyllotoxin Analoga (pages 365-380): Torsten Linker, Ulrike Engelhardt and Arunkanti SarkarChapter 5 Preparation of Optically Active Hydroperoxides and Their Use for Stereoselective Oxygen Transfer (pages 381-405): Hans?Jurgen Hamann, Eugen Hoft and Jurgen LiebscherChapter 6 New Early Transition?Metal Complexes as Homogeneous Catalysts for Olefin Oxidation (pages 406-432): Wolfgang A. Herrmann, Jorg Fridgen and Joachim J. HaiderChapter 7 Olefin Epoxidation Catalyzed by Molybdenum Peroxo Complexes: A Mechanistic Study (pages 433-453): Werner R. Thiel, Michael Barz, Holger Glas and Anna?Katharina PleierChapter 8 Oxidation Reactions in Perfluorinated Solvents (pages 454-468): Bodo Betzemeier and Paul KnochelChapter 9 Transition?Metal Alkoxide?Catalyzed Oxidation of Phenols, Alcohols, and Amines with tert.?Butyl hydroperoxide (pages 469-493): Horst Adam, Karameli Khanbabaee, Karsten Krohn, Jochen Kupke, Hagen Rieger, Klaus Steingrover and Ingeborg VinkeChapter 10 Enantioselective Baeyer-Villiger Reactions and Sulfide Oxidations (pages 494-510): Carsten BolmChapter 11 Chiral Pentacoordinated Manganese Complexes As Biomimetic Catalysts for Asymmetric Epoxidations with Hydrogen Peroxide (pages 511-525): Albrecht Berkessel, Thomas Schwenkreis, Matthias Frauen?Kron, Adrian Steinmetz, Norbert Schatz and Jochen ProxChapter 12 Photocatalytic Activation of Oxygen by Iron(III)porphyrins (pages 526-541): Horst Hennig and Doritt LuppaChapter 13 Oxidation and Oxygenation of Substituted Arenes with Alkyl Hydroperoxides or Dioxygen/Mediation by Schiff?Base Complexes (pages 542-566): Anton Rieker, Stefan Forster and Emerich EichhornChapter 1 The Nature of the Transition Structures for Oxygen Atom Transfer from Peroxy Acids, Dioxiranes and Chiral Bis(silyl) Peroxides (pages 567-600): Robert D. BachChapter 2 Mechanistic Aspects of Transition?Metal?Catalyzed Olefin Epoxidation from Density Functional Studies (pages 601-619): Notker Rosch, Philip Gisdakis, Ilya V. Yudanov and Cristiana Di ValentinChapter 3 Near?UV Photolysis of Singlet Oxygen Generated by Energy Transfer from Aromatic Molecules in Rare?Gas Matrices (pages 620-639): Murthy S. Gudipati, Robert Wagner, Martin Kalb and Andreas KleinChapter 4 Transition?Metal Ion Chemistry of Peroxides in the Gas Phase (pages 640-664): Detlef Schroder, Christoph A. Schalley and Helmut Schwarz

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Tags: Peroxide, Chemistry, Mechanistic, Preparative, Aspects, Oxygen, Transfer

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